Liverpool will host Arsenal and Chelsea are to take on Manchester United in the League Cup fourth round ties.
Jurgen Klopp's Premier League leaders will face the Gunners at Anfield and struggling Man. United will head to Stamford Bridge.
Liverpool, who have won the competition a record eight times, beat Milton Keynes Dons 2-0 to reach the fourth round, while Arsenal thrashed Nottingham Forest 5-0.
Man. United, who last won the League Cup in 2017, needed a 5-3 penalty shoot-out victory over third tier Rochdale to limp through after a 1-1 draw at Old Trafford.
Last season's runners-up Chelsea hammered Grimsby 7-1.
Southampton will travel to title holders Manchester City after taking a win at local rivals Portsmouth.
Other two all-Premier League ties in the fourth round will feature Everton vs. Watford and Aston Villa vs. Wolves.
Leicester will travel to Burton. In an all-League One clash, Oxford will host Sunderland.
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